Single cyclized molecule structures from RAFT homopolymerization of multi-vinyl monomersw
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Single cyclized molecule structures from RAFT homopolymerization of multi-vinyl monomers.
We explore a kinetically controlled strategy to suppress the gelation in the homopolymerization of multi-vinyl monomers (MVMs) via RAFT polymerization. We report the generation of 3D single cyclized polymer structures from the RAFT process, which significantly contradicts the classic F-S theory. This approach enables synthesis of a new generation of nanosize macromolecular architectures.
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